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R. Turner, Macromol. , 102,47 (1996). 61. Y. H. Kim and O. W. Webster, J. Am. Chem. Soc, 112,4592 (1990). 62. M. Johansson and A. Hult, J. ), 35 (1995). 63. A. Hult, M. Johansson, and E. Malmstrom, Macromol. , 98, 1159 (1995). 64. O. A. Matthews, A. N. Shipway, and J. Fraser Stoddart, Prog. Polym. ScL, 23, 1 (1998). 65. Y. H. Kim, J. Polym. : Part A: Polym. , 36, 1685 (1998). 2 Star-Shaped Polymers via Anionic Polymerization Methods S. Plentz Meneghetti and P. J. Lutz Institute Charles Sadron, CNRS, Strasbourg, France D.

In spite of the hydrophobic poly(DVB) core that constitutes up to 5% of the overall weight, these star-shaped PEOs are soluble in methanol or even in water. The molar masses of the star PEO macromolecules are systematically measured in methanol, a good solvent of PEO, in which the association phenomena are limited. As mentioned earlier these star-shaped polymers obtained from polyfunctional initiators are characterized by the presence of active sites located at the outer end of the branches. Thus a large variety of structures can be prepared from these functional star-shaped polymers.

J. Frechet, Science, 263, 1710(1994). B. I. , 46, 87 (1995). J. M. J. Frechet and C. J. Hawker, in Comprehensive Polymer Science, Second Supplement, S. I. Aggarwal and S. Y, New York, 1996. L. J. , J. I. , Wiley, New York, Vol. 10,1987, p. 19. H. Hsieh, Rubber Chem. Technol, 49, 1305 (1976). R. P. Quirk, D. J. Kinning, and L. J. Fetters, in Comprehensive Polymer Science, G. Allen and J. C. Y, Vol. 7,1989, p. 1. M. Morton, T. E. Helminiak, S. D. Gadkary, and F. Bueche, J. Polym. , 57,471 (1962).

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