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There's an expanding problem for chemical and examine associations to discover reasonably priced and environmentally sound tools of changing traditional assets into fuels chemical compounds and effort. Catalysts are necessary to those methods and the Catalysis expert Periodical document sequence serves to spotlight significant advancements during this sector.
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Additional resources for Catalysis by Polymers
Sharma, J. Schubert, J. Am. Chem. 91, 6291 (1969); 92, 822 (1970)  H. Sigel, Angew. Chem. Int. Ed. Engl. A. Bekturov, S. E. B. Sigitov, Polymer 27, 1269 (1986)  V. B. Sigitov, S. E. Kudaibergenov, E. A. Bekturov, Koord. Khim. 13, 600 (1987)  P. G. Meinders, G. Challa, in Polymeric Amines and Ammonium Salts. E. J. Goethals, editor Pergamon Press Oxford, New York, Toronto, Sydney, Paris, Frankfurt, 1980  M. Takeishi, M. Ueda, Sh. Hayama, Makromol. , Rapid Commun. 2, 167 (1981)  T.
Whenever an equivalent amount of the second metal is added to a P4VP-copper complex, the activity of the particular mixed polymermetal complexes changes. For instance, manganese ions promote the catalytic activity of this complex, whereas chromium and iron ions inhibit it. A mixed P4VP-Cu(II), Mn(II1) complex increases not only the reaction rate but also the yield and molecular weight of PPO. A rapid oxidation-reduction reaction as depicted below is expected in the presence of Mn ions: Cu(I)+Mn(III) P4VP Cu(II)+Mn(II) As a result, DMP oxidation in the presence of the mixed catalyst involves the following cycles: The substrate coordinates with the copper complex and thereby becomes activated.
Chem. 180, 1099 (1979)  T. M. P. L. Khidekel, Izv. Akad. Nauk SSSR, Ser. Khim.